Dr. Matthias Künzel

Organisationseinheit

Akademie-Kolleg

Adresse
Karlsruher Institut für Technologie (KIT)
Helmholtz Institut für Elektrochemische Enegiespeicherung Ulm (HIU)
Helmholtzstrasse 11
89081 Ulm
Tel
+49 (0) 731 50 34114

Curriculum Vitae

Akademischer Werdegang

Seit 01/2020

Wissenschaftler (Postdoktorand), Karlsruher Institut für Technologie (KIT), Karlsruhe und Helmholtz Institut Ulm (HIU), Ulm

12/2016 – 12/2019

Wissenschaftlicher Mitarbeiter (Doktorand), Karlsruher Institut für Technologie (KIT), Karlsruhe und Helmholtz Institut Ulm (HIU), Ulm

10/2014 – 09/2016

M.Sc. Molecular Nano Science, Friedrich-Alexander Universität (FAU), Erlangen-Nürnberg und Robert Bosch GmbH, Renningen (Masterarbeit)

07/2015 – 12/2015

ISAP-Stipendium des DAAD, Forschungsaufenthalt in Australien, University of Wollongong (UoW), Wollongong (Australien)

10/2011 – 09/2014

B.Sc. Molecular Nano Science, Friedrich-Alexander Universität (FAU), Erlangen-Nürnberg

 

Forschungsschwerpunkte

Kobaltfreie Kathodenmaterialien für Lithium-Ionen Batterien

Wasserlösliche Binder und wasserbasierte Elektrodenfertigung

Elektrolyt- und Prozessadditive für Hochvolt-Spinell Kathoden

Alternative Anoden- und Natrium-Ionen Batterie Elektroden

 

 

Lehrerfahrung

Vorlesungen & Seminare

Seminar zur Vorlesung “Elektrochemie”: SoSe 2021 (1SWS)

 

Betreuung & Mitorganisation von Laborpraktika

Physikalische Chemie für Anfänger: SoSe 2018 (1SWS)

Physikalische Chemie für Chemieingenieure: WiSe 2018 (1SWS)

Physikalische Chemie für Chemieingenieure: WiSe 2017 (1SWS)

 

Betreuung von Masterstudenten

Timo Böhler (02/2021 – 10/2021), Masterarbeit

Markus Binder (06/2020 – 02/2021), Masterarbeit

Vidur Kumar (01/2020 – 09/2020), Masterarbeit

Hyeongseon Choi (01/2019 – 09/2019), Masterarbeit

Regis Porhiel (06/2018 – 08/2018), Auslandspraktikum

 

Auszeichnungen

2021 Gips-Schüle-Nachwuchspreis, Gips-Schüle Stiftung

2021 Ökologiepreis der Viktor & Sigrid Dulger Stiftung, Heidelberger Akademie der Wissenschaften d. Landes Baden-Württemberg

2020 13. KIT-Doktorandenpreis, Karlsruhe Institut für Technologie (KIT)

2020 ECS Battery Division Student Research Award, Mercedes-Benz Research & Development

2015 ISAP-Stipendium, Deutscher Akademischer Austauschdienst (DAAD)

2013 Deutschlandstipendium, Evonik u. Friedrich-Alexander Universität

 

 

Ausgewählte Publikationen und Vorträge

Top-drei ausgewählte Publikationen

  • Kuenzel et al. Complementary Strategies Toward the Aqueous Processing of High-Voltage LiNi0.5Mn1.5O4 Lithium-Ion Cathodes. ChemSusChem 2018, 11 (3), 562-573.
  • Kuenzel et al. Crystal Engineering of TMPOx-coated LiNi0.5Mn1.5O4 Cathodes for High-Performance Lithium-Ion Batteries. Materials Today 2020, 39, 127-136.
  • Kuenzel et al.*= The success story of graphite as a lithium-ion anode material – fundamentals, remaining challenges, and recent developments including silicon (oxide) composites. Sustainable Energy & Fuels 2020, 4, 5387-5416.

 

 

Vollständige Publikationsliste in wissenschaftlichen Journalen

  1. Kumar, V.; Kuenzel, M.; Zarrabeitia, M.; Diemant, T.; Jusys, Z.; Behm, R. J.; Bresser, D.; Passerini, S. High-Voltage stabilized 5V Li-Ion Cathodes through a Mild Fluorination Treatment. Journal 2021, in preparation.
  2. Binder, M.; Kuenzel, M.; Diemant, T.; Jusys, Z.; Behm, R. J.; Binder, J. R.; Stock, S.; Diller, F.; Daub, R.; Bresser, D.; Passerini, S. Investigation of a Ternary Additive Mixture for Suppressed Electrolyte Decomposition and Mitigated Gassing in 5V LNMOGraphite Li-Ion Cells. Journal of Power Sources 2021, submitted manuscript.
  3. Han, J.; Euchner, H.; Kuenzel, M.; Hosseini, S. M.; Groß, A.; Varzi, A.; Passerini, S. A Thin and Uniform Fluoride-Based Artificial Interphase for the Zinc Metal Anode Enabling Reversible Zn/MnO2 Batteries. ACS Energy Letters 2021, 6, 3063-3071.
  4. Chen, Z.; Kim, G. T.; Kim, J. K.; Zarrabeitia, M.; Kuenzel, M.; Liang, H. P.; Geiger, D.; Kaiser, U.; Passerini, S. Highly Stable QuasiSolidState Lithium Metal Batteries: Reinforced Li1.3Al0.3Ti1.7(PO4)3/Li Interface by a Protection Interlayer. Advanced Energy Materials 2021, 11(30), 2101339.
  5. Wu, F.; Schür, A. R.; Kim, G. T.; Dong, X.; Kuenzel, M.; Diemant, T.; D'Orsi, G.; Simonetti, E.; De Francesco, M.; Bellusci, M.; Appetecchi, G. B.; Passerini, S. A novel phosphonium ionic liquid electrolyte enabling high-voltage and high-energy positive electrode materials in lithium-metal batteries. Energy Storage Materials 2021, 42, 826-835.
  6. Wu, F.; Fang, S.; Kuenzel, M.; Mullaliu, A.; Kim, J.-K.; Gao, X.; Diemant, T.; Kim, G.-T.; Passerini, S. Dual-anion ionic liquid electrolyte enables stable Ni-rich cathodes in lithium metal batteries. Joule 2021, 5(8), 2177-2194.
  7. Steinle, D.; Chen, Z.; Nguyen, H.-D.; Kuenzel, M.; Iojoiu, C.; Passerini, S.; Bresser, D.; Single-ion conducting polymer electrolyte for Li||LiNi0.6Mn0.2Co0.2O2 batteries – impact of the anodic cutoff voltage and ambient temperature. Journal of Solid State Electrochemistry 2021, 4-9.
  8. Han, J.S.; Hwang, G.C.; Yu, H.; Lim, D.-H.; Cho, J.S.; Kuenzel, M.*; Kim, J.-K.; Ahn, J.-H. Preparation of fully flexible lithium metal batteries with free-standing β-Na0.33V2O5 cathodes and LAGP hybrid solid electrolytes. Journal of Industrial and Engineering Chemistry 2021, 94, 368-375.
  9. Kazzazi, A.; Bresser, D.; Kuenzel, M.; Hekmatfar, M.; Schnaidt, J.; Jusys, Z.; Diemant, T.; Behm, R. J.; Copley, M.; Maranski, K.; Cookson, J.; de Meatza, I.; Axmann, P.; Wohlfahrt-Mehrens, M.; Passerini, S. Synergistic electrolyte additives for enhancing the performance of high-voltage lithium-ion cathodes in half-cells and full-cells. Journal of Power Sources 2021, 482, 228975.
  10. Brutti, S.; Simonetti, E.; De Francesco, M.; Sarra, A.; Paolone, A.; Palumbo, O.; Fantini, S.; Lin, R.; Falgayrat, A.; Choi, H.; Kuenzel, M.; Passerini, S.; Appetecchi, G. B. Ionic liquid electrolytes for high-voltage lithium-ion batteries. Journal of Power Sources 2020, 479, 228791.
  11. Asenbauer, J.; Kuenzel, M.; Eisenmann, T.; Birozzi, A.; Chang, J.-K.; Passerini, S.; Bresser, D. Determination of the Volume Changes Occurring for Conversion/ Alloying-Type Li-Ion Anodes upon Lithiation/Delithiation. Journal of Physical Chemistry Letters 2020, 11 (XXX), 8238–8245.
  12. Asenbauer*=, J.; Eisenmann*=, T.; Kuenzel*=, M.; Kazzazi, A.; Chen, Z.; Bresser, D. The success story of graphite as a lithium-ion anode material – fundamentals, remaining challenges, and recent developments including silicon (oxide) composites. Sustainable Energy & Fuels 2020, 4, 5387-5416. (Front Cover)
  13. Kuenzel, M.; Choi, H.; Wu, F.; Kazzazi, A.; Axmann, P.; Wohlfahrt-Mehrens, M.; Bresser, D.; Passerini, S. Co-Crosslinked Water-Soluble Biopolymers as Superior Binder for High‑Voltage LiNi0.5Mn1.5O4|Graphite Lithium-Ion Full-Cells. ChemSusChem 2020, 13 (10), 2650-2660.
  14. Asenbauer, J.; Binder, J.; Mueller, F.; Kuenzel, M.; Geiger, D.; Kaiser, U.; Passerini, S.; Bresser, D. Scalable Synthesis of Microsized, Nanocrystalline Zn0.9Fe0.1O-C Secondary Particles and Their Use in Zn0.9Fe0.1O-C/LiNi0.5Mn1.5O4 Lithium-Ion Full Cells. ChemSusChem 2020, 13 (13), 3504-3513.
  15. Wu, F.; Kim, G.-T.; Diemant, T.; Kuenzel, M.; Schuer, A. R.; Gao, X.; Qin, B.; Alwast, D.; Jusys, Z.; Behm, R. J.; Geiger, D.; Kaiser, U.; Passerini, S. Reducing Capacity and Voltage Decay of Co-Free Li1.2Ni0.2Mn0.6O2 as Positive Electrode Material for Lithium Batteries Employing an Ionic Liquid-Based Electrolyte. Advanced Energy Materials 2020, 10 (34), 2001830. (Inside Front Cover)
  16. Kuenzel, M.; Kim, G.-T.; Zarrabeitia, M.; Lin, S. D.; Schuer, A.; Geiger, D.; Kaiser, U.; Bresser, D.; Passerini, S. Crystal Engineering of TMPOx-coated LiNi0.5Mn1.5O4 Cathodes for High-Performance Lithium-Ion Batteries. Materials Today 2020, 39, 127-136.
  17. Quartarone, E.; Eisenmann, T.; Kuenzel, M.; Tealdi, C.; Marrani, A. G.; Brutti, S.; Callegari, D.; Passerini, S. Towards Advanced Sodium-Ion Batteries: Green, Low-Cost and High-Capacity Anode Compartment Encompassing Phosphorus/Carbon Nanocomposite as the Active Material and Aluminum as the Current Collector. Journal of The Electrochemical Society 2020, 167 (8), 080509.
  18. Kuenzel, M.; in het Panhuis, M.; Strain sensors based on conducting poly(acrylamide) hydrogels. MRS Advances 2020, 5 (17), 917-925.
  19. Ma, Y.; Ma, Y.; Giuli, G.; Euchner, H.; Groß, A.; Lepore, G. O.; d'Acapito, F.; Geiger, D.; Kaiser, U.; Diemant, T.; Behm, R. J.; Kuenzel, M.; Passerini, S.; Bresser, D. Introducing Highly Redox-Active Atomic Centers into Insertion-Type Electrodes for Lithium-Ion Batteries. Advanced Energy Materials 2020, 10 (25), 2000783.
  20. Pervez, S. A.; Kim, G.-T.; Bhaghavathi, V. P.; Cambaz, M. A.; Kuenzel, M.; Hekmatfar, M.; Fichtner, M.; Passerini, S. Overcoming the Interfacial Limitations Imposed by the Solid-Solid Interface in Solid-State Batteries using Ionic Liquid-based Interlayers. Small 2020, 11 (32), 28885-28893.
  21. Kuenzel, M.; Porhiel, R.; Bresser, D.; Asenbauer, J.; Axmann, P.; Wohlfahrt-Mehrens, M.; Passerini, S. Deriving StructurePerformance Relations of Chemically Modified Chitosan Binders for Sustainable HighVoltage LiNi0.5Mn1.5O4 Cathodes. Batteries & Supercaps 2020, 3 (2), 155-164. (Front Cover)
  22. Kuenzel, M.; Bresser, D.; Kim, G.-T.; Axmann, P.; Wohlfahrt-Mehrens, M.; Passerini, S. Unveiling and Amplyfying the Benefits of Carbon-Coated Aluminum Current Collectors for Sustainable HighVoltage LiNi0.5Mn1.5O4 Cathodes. ACS Applied Energy Materials 2019, 3 (1), 218-230.
  23. Wu, F.; Kim, G.-T.; Kuenzel, M.; Zhang, H.; Asenbauer, J.; Geiger, D.; Kaiser, U.; Passerini, S. Elucidating the Effect of Iron Doping on the Electrochemical Performance of CobaltFree LithiumRich Layered Cathode Materials. Advanced Energy Materials 2019, 9 (43), 1902445. (Inside Back Cover)
  24. Zarrabeitia, M.; Gomes Chagas, L.; Kuenzel, M.; Gonzalo, E.; Rojo, T.; Passerini, S.; Muñoz-Márquez, M. Á. Toward Stable Electrode/Electrolyte Interface of P2-Layered Oxide for Rechargeable Na-Ion Batteries. ACS Appl. Mater. Interfaces 2019, 11 (32), 28885-28893.
  25. Abeywardana, M. Y.; Laszczynski, N.; Kuenzel, M.; Bresser, D.; Passerini, S.; Lucht, B. Increased Cycling Performance of Li-Ion Batteries by Phosphoric Acid Modified LiNi0.5Mn1.5O4 Cathodes in the Presence of LiBOB. Int. J. Electrochem. 2019, 2019, 1-7.
  26. Kuenzel, M.; Bresser, D.; Diemant, T.; Carvalho, D. V.; Kim, G. T.; Behm, R. J.; Passerini, S. Complementary Strategies Toward the Aqueous Processing of High-Voltage LiNi0.5Mn1.5O4 Lithium-Ion Cathodes. ChemSusChem 2018, 11 (3), 562-573. (Cover Feature)

 

Patente

  1. EP-17-401-101.5 (2017), D. Bresser, M. Kuenzel, S. Passerini – Electrode material for lithium-ion batteries and method for preparing the same.

 

Vorträge auf internationalen Tagungen

  • M. Kuenzel, V. Kumar, A.R. Schür, M. Binder, D. Bresser, S. Passerini – Stabilizing the Interfaces in High-Voltage Li-Ion Cathodes. Annual Meeting of the International Society of Electrochemistry (ISE), Jeju Island, Korea, 29.08.-03.09. 2021, Oral presentation.
  • M. Kuenzel, A. Kazzazi, D. Bresser, S. Passerini – Sustainable High-Performance Lithium-Ion Batteries: Aqueous Processing of Cobalt-Free High-Energy Cathodes. PRiME 2020 Meeting of the Electrochemical Society (ECS), Honolulu, USA, 04.10.-09.10. 2020, Invited oral presentation & ECS Battery Division Student Research Award.
  • M. Kuenzel, D. Bresser, S. Passerini – Li-Ion Batteries: From High Energy to Sustainability. Annual Meeting of the International Society of Electrochemistry (ISE), Belgrade, Serbia, 30.08.-04.09. 2020, Invited oral presentation.
  • M. Kuenzel, A. Kazzazi, G.-T. Kim, D. Bresser, S. Passerini – Towards the Realization of Sustainable High-Performance Lithium-Ion Batteries: Aqueous Processing of Cobalt-free High-Energy Cathodes. 236th Meeting of the Electrochemical Society (ECS), Atlanta, USA, 13.10.-17.10. 2019, Invited oral presentation.
  • M. Kuenzel, G.-T. Kim, D. Bresser, S. Passerini – MPOx Coated High-Voltage LiNi0.5Mn1.5O4 with Tailored Morphology for High-Power Lithium-Ion Full-Cells. European Materials Research Society (E-MRS) Spring Meeting, Nice, France, 27.05.-31.05. 2019, Oral presentation.
  • M. Kuenzel, G.-T. Kim, D. Bresser, S. Passerini – Towards the Realization of Aqueous Electrode Processing for Sustainable High-Energy Lithium-Ion Cathodes. AiMES 2018 Meeting of the Electrochemical Society (ECS), Cancun, Mexico, 30.09.-04.10. 2018, Oral presentation & ECS Travel Grant.
  • M. Kuenzel, A. Kazzazi, D. Bresser, S. Passerini – Aqueous Electrode Processing for High-Energy Lithium-Ion Cathodes. Annual Meeting of the International Society of Electrochemistry (ISE 2018), Bologna, Italy, 02.09.-07.09. 2018, Oral presentation.
  • M. Kuenzel, D. Bresser, D. V. Carvalho, G.-T. Kim, T. Diemant, J. Behm, S. Passerini – Complementary strategies towards the aqueous processing of high-voltage LiNi0.5Mn1.5O4 lithium-ion cathodes: Crosslinking CMC and phosphoric acid treatment. European-Materials Research Society (E-MRS) Fall Meeting, Warsaw, Poland, 18.09.-21.09. 2017, Oral presentation.
  • M. Kuenzel, D. Bresser, S. Passerini – Complementary strategies towards the aqueous processing of high-voltage LiNi0.5Mn1.5O4 lithium-ion cathodes. German-Israeli Battery School (GIBS), Haifa, Israel, 12.09.-14.09. 2017, Oral presentation.